硝酸苯酯

硝酸苯酯(Nitric acid, phenyl ester)是氯甲酸苯酯硝酸银乙腈溶液反应得到的中间体,该中间体通过重排反应转变为邻硝基苯酚[1]

很多相似的重排反应也被观察到,如苯硝胺转变为o-硝基苯胺的反应是分子内的重排反应。[2]

註釋

  1. Alan Chaney, M Wolfrom. An Attempted Synthesis of Phenyl Nitrate. J. Org. Chem., 1961, 26 (8), pp 2998–2998. DOI: 10.1021/jo01066a614
  2. S. Brownstein, C.A. Bunton, E.D. Hughes. Chem. & Ind. (London), 981 (1956)

参考文献

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