1-硝基萘

1-硝基萘是一种有机化合物,化学式为C10H7NO2。它可由的硝化反应制备,混酸是最常见的硝化试剂,[4][5]也有文献报道使用硝酸铋[6]二氧化氮[7]N-硝基糖精[8]等进行硝化反应。它可以被还原剂(如氢气[9]硼氢化钠[10]水合肼[11]等)还原为1-萘胺

1-硝基萘
别名 α-硝基萘
识别
CAS号 86-57-7  
PubChem 6849
ChemSpider 6588
SMILES
Beilstein 1867714
UN编号 2538
EINECS 201-684-5
ChEBI 34104
KEGG C14040
性质
化学式 C10H7NO2
摩尔质量 173.17 g·mol−1
外观 浅黄色固体
密度 1.332 g·cm−3[1]
熔点 59 °C(332 K)[2]
溶解性 0.0035 g(25 °C)[3]
危险性
GHS危险性符号
GHS提示词 危险
H-术语 H228, H301, H315, H319, H335, H351, H411
P-术语 P201, P202, P210, P240, P241, P261, P264, P270, P271, P273, P280, P281, P301+310, P302+352
若非注明,所有数据均出自一般条件(25 ℃,100 kPa)下。

参考文献

  1. "Hazardous Substances Data Bank" data were obtained from the National Library of Medicine (US). Retrieved from SciFinder. [2020-12-28].
  2. Badgujar, D. M.; Talwar, M. B.; Asthana, S. N.; Mahulikar, P. P. Environmentally benign synthesis of aromatic nitro compounds using silica supported inorganic nitrates. Journal of Scientific & Industrial Research, 2007. 66 (3): 250-251. ISSN: 0022-4456.
  3. Calculated using Advanced Chemistry Development (ACD/Labs) Software V11.02 (© 1994-2020 ACD/Labs). Retrieved from SciFinder. [2020-12-28].
  4. Khabarov, Yu. G.; Veshnyakov, V. A.; Snigirev, I. A. Method for producing 1-nitronaphthalene. 2018. RU 2669774 C1.
  5. Gerald Booth. Wiley-VCH Verlag GmbH & Co. KGaA , 编. . Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA. 2000-06-15 [2020-12-28]. ISBN 9783527306732. doi:10.1002/14356007.a17_009 (英语).
  6. Susanta Samajdar, Frederick F Becker, Bimal K Banik. . Tetrahedron Letters. 2000-10, 41 (42): 8017–8020 [2020-12-28]. doi:10.1016/S0040-4039(00)01397-6. (原始内容存档于2018-06-27) (英语).
  7. Kuiyi You, Zhongcang Zhou, Jian Jian, Renjie Deng, Pingle Liu, Qiuhong Ai, He’an Luo. . Research on Chemical Intermediates. 2015-11, 41 (11): 8307–8315 [2020-12-28]. ISSN 0922-6168. doi:10.1007/s11164-014-1893-1 (英语).
  8. Roxan Calvo, Kun Zhang, Alessandro Passera, Dmitry Katayev. . Nature Communications. 2019-12, 10 (1) [2020-12-28]. ISSN 2041-1723. PMC 6667458. PMID 31363083. doi:10.1038/s41467-019-11419-y. (原始内容存档于2019-11-15) (英语).
  9. Huan Fu, Luna Ruan, Jianhua Liao, An Pei, Jun Liu, Li Zeng, Kai Yang, Lihua Zhu, Bing Hui Chen. . Molecular Catalysis. 2020-10, 494: 111151 [2020-12-28]. doi:10.1016/j.mcat.2020.111151 (英语).
  10. Haydar Göksu, Nursefa Zengin, Hakan Burhan, Kemal Cellat, Fatih Şen. . Scientific Reports. 2020-12, 10 (1) [2020-12-28]. ISSN 2045-2322. PMC 7229225. PMID 32415148. doi:10.1038/s41598-020-64988-0 (英语).
  11. Upendra Sharma, Praveen Kumar Verma, Neeraj Kumar, Vishal Kumar, Manju Bala, Bikram Singh. . Chemistry - A European Journal. 2011-05-16, 17 (21): 5903–5907 [2020-12-28]. doi:10.1002/chem.201003621 (英语).
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