氯酸鋰
氯酸鋰是一種無機化合物,屬於氯酸鹽,為一種鹽類,其化學式為LiClO3。氯酸鋰是一種氧化劑,在高溫下則是強氧化劑。
氯酸鋰 | |||
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别名 | 三氧化氯鋰, 鋰鹽 | ||
识别 | |||
CAS号 | 36355-96-1 | ||
PubChem | 61612 | ||
ChemSpider | 55520 | ||
SMILES |
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InChI |
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性质 | |||
化学式 | LiClO3 | ||
摩尔质量 | 90.39 g·mol⁻¹ | ||
熔点 | 127.6-129 °C[1][2][3] | ||
沸点 | 270 °C (分解)[4] | ||
溶解性(水) | 313.5 g·100 ml (18 °C)[4] | ||
相关物质 | |||
其他阴离子 | 氯化鋰 高氯酸鋰 次氯酸鋰 | ||
其他阳离子 | 氯酸钠 氯酸钾 氯酸銣 氯酸銫 | ||
若非注明,所有数据均出自一般条件(25 ℃,100 kPa)下。 |
制備
- Li2CO3 + HClO3 → 2LiClO3 + CO2↑
- Li2SO4 + Ba(ClO3)2 → LiClO3 + BaSO4↓
用途
氯酸鋰用在火箭推進劑的氧化劑。[5]
參考文獻
- S. S. Wang, D. N. Bennion: "The Electrochemistry of Molten Lithium Chlorate and Its Possible Use with Lithium in a Battery" in J. Electrochem. Soc. 1983, 130(4), S. 741-747. Abstract
- A. N. Campbell, E. M. Kartzmark, W. B. Maryk: "The Systems Sodium Chlorate - Water - Dioxane and Lithium Chlorate - Water - Dioxane, at 25°" in Can. J. Chem. 1966, 44, S. 935-937. Volltext
- http://scitation.aip.org/getabs/servlet/GetabsServlet?prog=normal&id=JESOAN000130000004000741000001&idtype=cvips&gifs=yes&ref=no
- R. Abegg, F. Auerbach, I. Koppel: Handbuch der anorganischen Chemie. Verlag S. Hirzel, 1908, 2. Band, 1. Teil, S. 136. Volltext
- E.-C. Koch: "Special Materials in Pyrotechnics: III. Application of Lithium and its Compounds in Energetic Systems" in Propellants, Explosives, Pyrotechnics 2004, 29(2). S. 67-80. doi:10.1002/prep.200400032
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