沃尔夫重排反应

沃尔夫重排反应Wolff重排反应),即:α-重氮[1][2]过渡金属催化剂(如氧化银)作用下,放出氮气生成卡宾中间体,然后发生1,2-重排反应生成烯酮[3][4][5]该反应由陆德维希·沃尔夫在1912年发现。[6]

Wolff重排反应

参见

参考资料

  1. Wheeler, T. N.; Meinwald, J. Org. Syn., Coll. Vol. 6, p.840 (1988); Vol. 52, p.53 (1972) (Article)
  2. Smith, L. I.; Hoehn, H. H. Org. Syn., Coll. Vol. 3, p.356 (1955); Vol. 20, p.47 (1940) (Article)
  3. Meier, H.; Zeller, K.-P. Angew. Chem. Int. Ed. Engl. 1975, 14, 32-43. (Review)
  4. Gill, C. B. Comp. Org. Syn. 1991, 3, 887-912. (Review)
  5. Kirmse, W. Eur. J. Org. Chem. 2002, 2002, 2193-2256. (Review)
  6. Ludwig Wolff Ann. 1912, 394, 25.
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