三乙基铝

三乙基铝
	IUPAC名; Triethylalumane
别名	乙基铝
识别
缩写	TEA,[1] TEAl,[2] TEAL[3]
CAS号	97-93-8
PubChem	16682930
ChemSpider	10179159
SMILES	CC[Al](CC)CC;
InChI	1/3C2H5.Al/c31-2;/h31H2,2H3;/rC6H15Al/c1-4-7(5-2)6-3/h4-6H2,1-3H3;
InChIKey	VOITXYVAKOUIBA-DVVALISXAR
EINECS	202-619-3
性质
化学式	C12H30Al2
摩尔质量	228.33 g·mol−1
外观	无色液体
密度	0.8324 g·cm−3（25 °C）
熔点	−52.5 °C（220.7 K）[4]
沸点	128～130 °C（401～403 K）（50 mmHg）[5]
危险性
警示术语	R：R14 R17 R34
安全术语	S：S16 S43 S45
主要危害	易自燃
NFPA 704	4 3 3
闪点	−18 °C（255 K）
相关物质
相关化学品	三甲基铝
	若非注明，所有数据均出自一般条件（25 ℃，100 kPa）下。

三乙基铝是一种金属有机化合物，化学式为Al₂(C₂H₅)₆。它是挥发性的无色液体，遇空气自燃。它可以纯品保存于不锈钢容器中，或溶于烃类溶剂储存。它是齐格勒-纳塔催化剂的必要组分。[6]

制备

三乙基铝可由铝、氢气和乙烯的化合反应制得：[7]

2 Al + 3 H₂ + 6 C₂H₄ → Al₂(C₂H₅)₆

铝粉和氯乙烷反应，得到倍半氯化乙基铝，它经金属钠还原后得到三乙基铝：[8]

3 Al₂Cl₃(C₂H₅)₃ + 9 Na → 2 Al₂(C₂H₅)₆ + 2 Al + 9 NaCl

此外，三丙基铝和乙烯反应[6]、二乙基汞[6]或三乙基镓[9]在加热下和铝反应，也能制得三乙基铝。

反应

三乙基铝的Al–C键具有极性，接受质子后放出乙烷：[10]

Al₂(C₂H₅)₆ + 6 HX → 2 AlX₃ + 6 C₂H₆

像醇或端基炔烃这样的弱酸也能参与反应，例如它和异丙醇反应，得到二乙基异丙醇铝；[11]和苯乙炔反应，得到二乙基(苯乙炔基)铝。[12]

它和四氯化锡在乙醚中反应，得到三乙基氯化锡。[13]它和氯化锌反应，生成二乙基锌：[7]

Al₂(C₂H₅)₆ + ZnCl₂ → Zn(C₂H₅)₂ + 2 (C₂H₅)₂AlCl

参考文献

Mission Status Center, June 2, 2010, 1905 GMT Archived 2010-06-04 at WebCite, SpaceflightNow, accessed 2010-06-02, Quotation: "The flanges will link the rocket with ground storage tanks containing liquid oxygen, kerosene fuel, helium, gaserous nitrogen and the first stage ignitor source called triethylaluminum-triethylborane, better known as TEA-TAB."
. Gulbrandsen. [December 12, 2017]. （原始内容存档于2017-12-13）. Triethylaluminum (TEAl) is a pyrophoric liquid...
Malpass, Dennis B.; Band, Elliot. . John Wiley & Sons. 2012. ISBN 9781118463208.
Pitzer, Kenneth S.; Gutowsky, Herbert S. Electron-deficient molecules. II. Aluminum alkyls. Journal of the American Chemical Society, 1946. 68: 2204-2209. ISSN: 0002-7863. doi:10.1021/ja01215a027
Gallais, Fernand; de Loth, Philippe. Magnetooptical properties of two trialkylaluminums and of their addition compounds with aliphatic ethers. Compt. Rend., 1962. 255. 2755-2756.
无机化学丛书第二卷铍碱土金属硼铝镓分族. 科学出版社. pp 498. 7.3 有机铝化合物
Michael J. Krause, Frank Orlandi, Alfred T. Saurage, Joseph R. Zietz Jr. "Aluminum Compounds, Organic" in Ullmann's Encyclopedia of Industrial Chemistry 2002, Wiley-VCH, Weinheim. DOI: 10.1002/14356007.a01_543
Krause, M. J; Orlandi, F; Saurage, A T.; Zietz, J R, "Organic Aluminum Compounds" Wiley-Science 2002.
Starowieyski, Kazimierz; Kruk, Przemyslaw. Process for preparation of trialkylaluminum compounds from metallic aluminum by transmetalation with trialkylgallium compounds. 2006. PL 192855 B1.
Elschenbroich, C. ”Organometallics” (2006) Wiley-VCH: Weinheim. ISBN 978-3-527-29390-2
Kunicki, A. R.; Pasynkiewicz, S.; Jankowski, J.; Mank, B. Alkoxyalumoxanes (ROAlO)_n - Synthesis and properties. Polish Journal of Chemistry, 2004. 78 (10): 1857-1864. ISSN: 0137-5083.
Kanbur, Uddhav; Ellern, Arkady; Sadow, Aaron D. Alkynylaluminum Synthesis Catalyzed by a Zwitterionic Neodymium(III) Heterobimetallic Compound. Organometallics, 2018. 37 (23): 4409-4414. ISSN: 0276-7333. doi:10.1021/acs.organomet.8b00374
Neumann, Wilhelm P. Organotin compounds. I. New methods of preparation for tin tetraalkyls and alkyltin halides. Justus Liebigs Annalen der Chemie, 1962. 653. 157-163. ISSN: 0075-4617.

This article is issued from Wikipedia. The text is licensed under Creative Commons - Attribution - Sharealike. Additional terms may apply for the media files.

[spaceflightnow-1] Mission Status Center, June 2, 2010, 1905 GMT Archived 2010-06-04 at WebCite, SpaceflightNow, accessed 2010-06-02, Quotation: "The flanges will link the rocket with ground storage tanks containing liquid oxygen, kerosene fuel, helium, gaserous nitrogen and the first stage ignitor source called triethylaluminum-triethylborane, better known as TEA-TAB."

[2] . Gulbrandsen. [December 12, 2017]. （原始内容存档于2017-12-13）. Triethylaluminum (TEAl) is a pyrophoric liquid...

[3] Malpass, Dennis B.; Band, Elliot. . John Wiley & Sons. 2012. ISBN 9781118463208.

[4] Pitzer, Kenneth S.; Gutowsky, Herbert S. Electron-deficient molecules. II. Aluminum alkyls. Journal of the American Chemical Society, 1946. 68: 2204-2209. ISSN: 0002-7863. doi:10.1021/ja01215a027

[5] Gallais, Fernand; de Loth, Philippe. Magnetooptical properties of two trialkylaluminums and of their addition compounds with aliphatic ethers. Compt. Rend., 1962. 255. 2755-2756.

[wuji-6] 无机化学丛书第二卷铍碱土金属硼铝镓分族. 科学出版社. pp 498. 7.3 有机铝化合物

[Ullmann-7] Michael J. Krause, Frank Orlandi, Alfred T. Saurage, Joseph R. Zietz Jr. "Aluminum Compounds, Organic" in Ullmann's Encyclopedia of Industrial Chemistry 2002, Wiley-VCH, Weinheim. DOI: 10.1002/14356007.a01_543

[8] Krause, M. J; Orlandi, F; Saurage, A T.; Zietz, J R, "Organic Aluminum Compounds" Wiley-Science 2002.

[9] Starowieyski, Kazimierz; Kruk, Przemyslaw. Process for preparation of trialkylaluminum compounds from metallic aluminum by transmetalation with trialkylgallium compounds. 2006. PL 192855 B1.

[10] Elschenbroich, C. ”Organometallics” (2006) Wiley-VCH: Weinheim. ISBN 978-3-527-29390-2

[11] Kunicki, A. R.; Pasynkiewicz, S.; Jankowski, J.; Mank, B. Alkoxyalumoxanes (ROAlO)_n - Synthesis and properties. Polish Journal of Chemistry, 2004. 78 (10): 1857-1864. ISSN: 0137-5083.

[12] Kanbur, Uddhav; Ellern, Arkady; Sadow, Aaron D. Alkynylaluminum Synthesis Catalyzed by a Zwitterionic Neodymium(III) Heterobimetallic Compound. Organometallics, 2018. 37 (23): 4409-4414. ISSN: 0276-7333. doi:10.1021/acs.organomet.8b00374

[13] Neumann, Wilhelm P. Organotin compounds. I. New methods of preparation for tin tetraalkyls and alkyltin halides. Justus Liebigs Annalen der Chemie, 1962. 653. 157-163. ISSN: 0075-4617.